作者：Lihua Yu, Sheng Zhang, Wei Liu, Xinjun Zhu, Xiaoping Chen, Xiaosui Chen
关键字：Photo-induced grafting; PET fabric; Flame retardancy
论文来源：期刊
发表时间：2010年

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  1
Improving the Flame Retardancy of PET Fabric by Photo-induced Grafting
 
Lihua Yu
a,b,c
, Sheng Zhang
a,b,c*
 ,Wei Liu
a
, Xinjun Zhu
a,c
, Xiaoping Chen
a
, Xiaosui Chen
 a
 
 
a
  Key  Laboratory  of  carbon  fiber  and  functional  polymers,  Ministry  of  Education,  Beijing
University of Chemical Technology, Beijing 100029, China  
b
 Beijing Key Laboratory on Preparation and Processing of Novel Polymeric Materials, Beijing
University of Chemical Technology, Beijing 100029, China
c
  State  Key  Laboratory  of  Chemical  Resource  Engineering,  Beijing  University  of  Chemical
Technology, Beijing 100029, China
?  
 
A B S T R A C T:
Photo-induced  surface  grafting  with  glycidyl  methacrylate  (GMA)  as  monomer  in
association  with  a  pad-curing  treatment  by  using  a  flame  retardant  (FR)  solution
which  contains  1-hydroxy  ethylidene-1,1-diphosphonic  acid  (HEDP)  and  sulfamic
acid  (H 2 NSO 3 H)    has  been  used  to  improve  the  fire  performance  of  PET  fabric  in
this  study.  The  effects  of  initiator  concentration,  monomer  concentration  and  the
irradiation time on the grafting percentage were investigated. The chemical structure
of  grafted  surface  of  the  PET  fabric  was  characterized  by  an  attenuated  total
reflection-infrared  (ATR-IR)  spectroscopy.  The  fire  performance  was  evaluated  by
the  LOI  and  the  vertical  flammability  tests,  and  the  results  indicate  that  the  photo
grafting treatment could improve the flame retardancy and dripping resistance of PET
fabric.  Thermal  behaviour  of  treated  PET  fabric  samples  was  investigated  by
thermogravimetric   (TG)   and   differential   scanning   calorimetric   (DSC).   The
morphology  of  the  sample  char  residue  was  also  investigated  by  scanning  electron
microscope (SEM).