当前位置:群英聚首 > 论文著作 > 正文
A New Level of Hierarchical Structure Control by Use of Supramolecular Self-assembled Dendronized Block Copolymers
来源:张阿方教授个人网站 发布日期:2010-08-12
作者:Chaoxu Li, A. Dieter Schlüter, Afang Zhang,* Raffaele Mazzenga*
关键字:block copolymer, morphology, dendronized polymer, thermoresponsive
论文来源:期刊
具体来源:Adv. Mater. 2008, 20, 4530-4534
发表时间:2008年

In the present work, we show that by replacing, in a block copolymer, the linear polymer block with a dendronized polymer capable of participating in supramolecular interactions, the additional degree of freedom arising from the varying generation of the dendronized polymer allows engineering the self-assembly into unprecedented hierarchically ordered bulk structures. Not only does this allow control of the structures at the smaller length scale beyond current possibilities with the introduction, for example, of new columnar-rectangular, -hexagonal and -tetragonal phases, but it may also lead to new functional template materials with increased 3D topological complexity for advanced technologies.

Copyright © 2005 Polymer.cn All rights reserved
中国聚合物网 版权所有
经营性网站备案信息

京公网安备11010502032929号

工商备案公示信息

京ICP证050801号

京ICP备12003651号