作者：He-xin Zhang Ho-young Lee Young-jun Shin Dong-ho Lee, Seok Kyun Noh
关键字：Styrene, POSS
论文来源：期刊
具体来源：Macromolecular Research May 2009, Volume 17, Issue 5, pp 352–355
发表时间：2009年

Copolymerization of St and St-POSS with and without 4-MeSt was carried out with half-titanocenes of Cp*TiCl3 catalyst and MMAO cocatalyst. The activity of catalyst and St-POSS content increased by the addition of 4-MeSt as the 3 rd monomer. The characteristic crystalline peak of St/St-POSS copolymer  was altered by incorporating of 4-MeSt. With increasing 4-MeSt contents, the glass transition temperature of the polymers increased and the  thermal stability was improved. The molecular weight and PDI of the polymers were not changed significantly with the incorporation of 4-MeSt.